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Solid State Ionics 34 (1989) 213-214 North-Holland, Amsterdam
BOOK REVIEWS Basic Solid State Chemistry. Anthony R. West, John Wiley & Sons, New 'York (1988), 415 pages £13.95 ($32.95). Solid State Chemistry and its Applications. Anthony R. West, John Wiley & Sons, N e w York (1987), 734 pages $103.00 hardcover, $39.95 softcover. Over the last few years, this book has become the standard text for courses in Solid State Chemistry. However, it has not achieved that standing without many complaints, most notably related to extraneous material, its order in the book and most of all the price, over $100.00, which precluded m a n y instrucors from making it required reading. This last was solved in 1988 by a paperback edition at about $40.00. The other issues have also been resolved to a major extent by the release of the new version titled 'Basic Solid State Chemistry'. In this latest reincarnation the author has not only introduced new material, such as the 1, 2, 3 s u p e r c o n d u c t o r s , and eliminated the more extraneous material in the old volume (concrete, condensed the discussion of phase diagrams) but also re-organized the chapters in content and order. The order, certainly for this review, is now much more consistent with how one teaches a solid state chemistry course. Thus the first chapter covers crystal structure, the second bonding in solids, and the third crystallography and diffraction techniques. The next covers very briefly other techniques, including microscopy, spectroscopy and thermal analysis; too short to be very useful but is a useful introduction for the student prior to further reading. Chapter 5 covers defects, nonstoichiometry and solid solutions and is followed by the Interpretation of Phase Diagrams, a good introduction for the student. The last two chapters cover Electrical Properties and Magnetic and Optical Properties. The first of these has been totally rewritten to incorporate organic conductors and oxide superconductors into the previous discussions of electronic properties and ionic conductivity. The second is essentially the old Chapters 16 and 17 without much change. West has collected some of the questions that used to be at the end of each chapter and placed them at the end of the book. Overall this is an
excellent book for a course in the foundations of solid state chemistry at either the upper division undergraduate level or as an introductory graduate course. Each instructor will no doubt want to add his or her special topics that have been omitted for the sake of brevity, but at the price and level this book is unbeatable. The author and publisher are to be commended for bringing out a quality text at a price affordable to students.
Solid State Chemistry. Techniques. Edited by A. K. Cheetham and P. Day, The Clarendon Press, Oxford University Press, New York (1987) 398 pages $70.00. In our earlier review [SSI, 26 (1988) 55] on this book we remarked that '..to gain wide acceptance publishers must price within the range acceptable to a student purse..'. This volume is now available in the UK in soft cover for £15.00, and should be available shortly in the U.S.
Impedance Spectroscopy. Edited by J. Ross Macdonald, A Wiley-Interscience Publication, John Wiley & Sons, New York (1987) 346 pages $44.95. This book is unusual in that the editor has participated in writing a number of the chapters, and appears to have gone to great lengths to make the individual contributions hang together as a whole. He has been remarkably successful. The book is divided into four sections covering Fundamentals of Impedance Spectroscopy (26 p), Theory (106 p), Measurement Techniques and Data Analysis (58 p), and Applications of Impedance Spectroscopy (126 p). This reader would have liked the third section to be somewhat longer with greater emphasis, for the novice, both on an analysis of the commercial equipment available, and on the subsequent analysis of the data obtained with some more discussion as to what model electrical circuits should or should not be chosen. However, much insight into techniques and data analysis can be gleaned from the fourth
BOOK REVIEWS Basic Solid State Chemistry. Anthony R. West, John Wiley & Sons, New 'York (1988), 415 pages £13.95 ($32.95). Solid State Chemistry and its Applications. Anthony R. West, John Wiley & Sons, N e w York (1987), 734 pages $103.00 hardcover, $39.95 softcover. Over the last few years, this book has become the standard text for courses in Solid State Chemistry. However, it has not achieved that standing without many complaints, most notably related to extraneous material, its order in the book and most of all the price, over $100.00, which precluded m a n y instrucors from making it required reading. This last was solved in 1988 by a paperback edition at about $40.00. The other issues have also been resolved to a major extent by the release of the new version titled 'Basic Solid State Chemistry'. In this latest reincarnation the author has not only introduced new material, such as the 1, 2, 3 s u p e r c o n d u c t o r s , and eliminated the more extraneous material in the old volume (concrete, condensed the discussion of phase diagrams) but also re-organized the chapters in content and order. The order, certainly for this review, is now much more consistent with how one teaches a solid state chemistry course. Thus the first chapter covers crystal structure, the second bonding in solids, and the third crystallography and diffraction techniques. The next covers very briefly other techniques, including microscopy, spectroscopy and thermal analysis; too short to be very useful but is a useful introduction for the student prior to further reading. Chapter 5 covers defects, nonstoichiometry and solid solutions and is followed by the Interpretation of Phase Diagrams, a good introduction for the student. The last two chapters cover Electrical Properties and Magnetic and Optical Properties. The first of these has been totally rewritten to incorporate organic conductors and oxide superconductors into the previous discussions of electronic properties and ionic conductivity. The second is essentially the old Chapters 16 and 17 without much change. West has collected some of the questions that used to be at the end of each chapter and placed them at the end of the book. Overall this is an
excellent book for a course in the foundations of solid state chemistry at either the upper division undergraduate level or as an introductory graduate course. Each instructor will no doubt want to add his or her special topics that have been omitted for the sake of brevity, but at the price and level this book is unbeatable. The author and publisher are to be commended for bringing out a quality text at a price affordable to students.
Solid State Chemistry. Techniques. Edited by A. K. Cheetham and P. Day, The Clarendon Press, Oxford University Press, New York (1987) 398 pages $70.00. In our earlier review [SSI, 26 (1988) 55] on this book we remarked that '..to gain wide acceptance publishers must price within the range acceptable to a student purse..'. This volume is now available in the UK in soft cover for £15.00, and should be available shortly in the U.S.
Impedance Spectroscopy. Edited by J. Ross Macdonald, A Wiley-Interscience Publication, John Wiley & Sons, New York (1987) 346 pages $44.95. This book is unusual in that the editor has participated in writing a number of the chapters, and appears to have gone to great lengths to make the individual contributions hang together as a whole. He has been remarkably successful. The book is divided into four sections covering Fundamentals of Impedance Spectroscopy (26 p), Theory (106 p), Measurement Techniques and Data Analysis (58 p), and Applications of Impedance Spectroscopy (126 p). This reader would have liked the third section to be somewhat longer with greater emphasis, for the novice, both on an analysis of the commercial equipment available, and on the subsequent analysis of the data obtained with some more discussion as to what model electrical circuits should or should not be chosen. However, much insight into techniques and data analysis can be gleaned from the fourth
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- Class 12 Chemistry Revision Notes for Chapter 1 - The Solid State - Free PDF Download Free PDF download of Class 12 Chemistry revision notes & short key-notes for Chapter 1 - The Solid State to score high marks in exams, prepared by expert Chemistry teachers from latest edition of CBSE(NCERT) books.
- Introduction Special aspects of solid state chemistry. Close relationship to solid state physics. Importance of structural chemistry. knowledge of several structure types. understanding of structures. Physical methods for the characterization of solids. X-ray structure analysis, electron microscopy. thermal analysis, spectroscopy, conductivity measurements.
- Solid State Chemistry PDF - Free download as PDF File (.pdf), Text File (.txt) or view presentation slides online. Scribd is the world's largest social reading and publishing site. Search Search.
- This page contains materials for the solid solutions class session on unary phase diagrams. It features a 1-hour lecture video, and also presents the prerequisites, learning objectives, reading assignment, lecture slides, homework with solutions, and resources for further study.
Session Overview
Modules | Solid Solutions |
Concepts | introduction to phase diagrams, basic definitions of phase, component, and equilibrium, one-component phase diagrams |
Keywords | stability, pressure, temperature, vapor, liquid, solid, phase, equilibrium, component, triple point, melting, boiling, glass transition temperature, polymorph, sublimation, supercritical |
Chemical Substances | water (H2O), zirconia (ZrO2), snowflake obsidian, aluminum (Al), silicon (Si), carbon dioxide (CO2), nitrogen (N), bismuth (Bi), sulfur (S), oxygen (O), argon (Ar), 'dry ice', carbon (C), mercury (Hg) |
Applications | failure analysis, cooking food at altitude and in pressure cooker, automobile engine cooling, ice skating, artificial diamonds, coffee decaffeination |
Prerequisites
Before starting this session, you should be familiar with:
- The Bonding and Molecules module, in particular Session 12: Intermolecular Forces
Looking Ahead
This is the first of three sessions on solid solutions and phase diagrams. Proceed to the next session, Session 34.
Solid State Chemistry and its Applications. West, John Wiley & Sons, N e w York (1987), 734 pages $103.00 hardcover, $39.95 softcover. Over the last few years, this book has become the standard text for courses in Solid State Chemistry. JGR: Solid Earth publishes original research articles on the broad field of solid Earth geophysics, petrology, geochemistry, mineralogy, tectonophysics, natural hazards, and volcanology.
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Learning Objectives
After completing this session, you should be able to:
- Summarize the purpose of a phase diagram.
- Give a detailed interpretation of the phase diagram of water.
- Given a set of material properties data, draw the phase diagram.
- Given a phase diagram, describe some properties of the material, e.g. the relative densities of its solid and liquid forms.
Reading
Archived Lecture Notes #10 (PDF), Part A
Book Chapters | Topics |
---|---|
[Saylor] 11.6, 'Critical Temperature and Pressure.' | Supercritical fluids; molten salts and ionic liquids |
[Saylor] 11.7, 'Phase Diagrams.' | General features of phase diagrams; phase diagrams of water and carbon dioxide |
Lecture Video
Flash and JavaScript are required for this feature.
Resources
Lecture Summary
Phase stability is the basis for the solid state of matter. Knowledge of phase stability enables applications like:
- conducting failure analysis -- recognizing phase 'signatures' in the material
- cooking at altitude -- adapting to different pressure/temperature relationships
- automobile engine cooling -- exploiting pressure and chemical composition to control the coolant's boiling point (a phase transition temperature)
Prof. Sadoway introduces phase diagrams as 'stability maps' and 'archives of pressure/temperature relationships.'
Solid State Chemistry Moore Pdf
This lecture defines and gives examples of phase, one phase and two phase systems, equilibrium, component, and triple point. A detailed discussion of the most familiar one phase system, water, is followed by comparisons of the phase diagrams of aluminum and silicon.
Prof. Sadoway does some live demonstrations for the class:
Solid State Chemistry Textbook Pdf
- various objects are immersed in liquid nitrogen, going below their glass transition temperature
- properties of liquid oxygen
- sublimation of solid frozen CO2, aka 'dry ice'
The phase diagram of zirconia illustrates the concept of changing a material's composition to produce desired behaviors at particular temperature/pressure conditions. The phase diagram of carbon illustrates how artificial diamonds are made. Bisumth and sulfur phase diagrams – 'phase diagrams from hell' – have many regions. Returning to water, Prof. Sadoway discusses the unusual phases of ice at very high pressures and very low temperatures.
As a final application note, the lecture ends with a quick summary of coffee decaffeination as a process employing sophisticated manipulation of phase transitions.
Homework
More phase diagram homework problems will be provided for the next two sessions.
For Further Study
Culture
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Other OCW and OER Content
Handbook Of Solid State Chemistry Pdf
Content | Provider | Level | Notes |
---|---|---|---|
3.012 Fundamentals of Material Science | MIT OpenCourseWare | Undergraduate (second-year) | See Thermodynamics lectures 15-16 on single-component phase diagrams, plus associated recitation and assignment content |
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Solid State Physical Chemistry Pdf
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